Japan Atomic Energy Agency has, in collaboration with Tohoku
University, Kyoto Sangyo University and Osaka University, succeeded
in observing Fermi surfaces (momentum distribution of the conduction
electrons) of a plutonium compound, for the first time in the
world.
Fermi surfaces, which is called as the "face" of metals,
characterize most of physical properties of metals. Fermi surfaces
of various compounds, including ordinary metals such as gold and
superconducting materials, have been investigated to reveal the
electronic properties of these materials. One of the powerful
methods to observe Fermi surface is the quantum oscillation of
magnetization which occurs at low-temperature under high magnetic
fields for a very pure specimen. In plutonium compounds, however,
the quantum oscillation has never been observed, due to their
strong radioactivity which causes damage to the plutonium compound
itself and lowers the quality of the specimen.
Very recently a plutonium compound PuIn3 with extremely high
quality has been grown by the flux method by scientists at the
Advanced Science Research Center, Japan Atomic Energy Agency.
The sample was encapsulated to prevent the radioactive contamination
and transported to the measurement facility rapidly to minimize
the effect of radiation damage. As a result, they have succeeded
in observing the quantum oscillation and determined the Fermi
surfaces of PuIn3. They also found that the conduction electrons
in PuIn3 have larger effective mass, several times heavier than
that of the free electron, and move around the sample.
Plutonium, which is known as a nuclear material, is one of the
most interesting elements because of its intriguing properties
such as the multiple structural transformations. It was also reported
recently that a plutonium-based superconductor with high-transition-temperature
was discovered, attracting much scientific interest. The present
observation that the 5f electron in plutonium compound moves around
as conduction electrons will contribute in understanding the extraordinary
high transition temperature of plutonium-based superconductors
as well as the cuprate superconductor, an important material for
the industrial application.
This result will be published as a Letter in the Journal of the
Physical Society of Japan in the November issue. It was selected
as one of the "Papers of Editors' Choice" of this journal.